Monday, May 28, 2012

Lithium 3D Solid-State Battery - Prieto Battery: How It Works

  Lithium batteries technology is developing very fast now. Envia Systems promises Electric cars for all and  now Prieto talks about safe, long lasting non-toxic Lithium 3D Solid-State Battery.

Envia - World's First 400 Wh/kg Lithium-ion Battery Poised to Revolutionize Cost, Range and Safety in EVs


The Chemistry Behind the Prieto Battery

This patent-pending architecture is designed around a nanowire array of anodes or porous carbon structure (copper foam), conformally coated by an ultra-thin polymer electrolyte and then surrounded by a cathode matrix. The result is a three-dimensionally structured lithium-ion battery composed of interpenetrating electrodes with extremely short Li+ diffusion distances and a power density that is orders of magnitude greater than comparable two-dimensional architectures in use today.
The use of copper antimonide (Cu2Sb) electrodeposited on nanowires or copper foam lends an unprecedented degree of stability to the anode and has already demonstrated virtually no loss of capacity over extensive cycling – a dramatic improvement over other anode materials. Such materials and the underlying technologies lend themselves to low cost manufacturing and production scale-up.
The realization of this sophisticated battery required the development of myriad cutting-edge enabling technologies. At the heart of this product is a patent-pending technology for the fabrication of the Cu2Sb nanowires & copper foam substrate? Using a novel electrodeposition method, Cu2Sb may be directly deposited as polycrystalline, intermetallic nanowires without the costly requirement of further annealing or other post-treatments. This technique ensures continuous electrical contact throughout the 3D anode.
The fabrication of the electrolyte layer is accomplished through an electrochemical polymerization method – specifically designed to uniformly encapsulate the entire conductive surface of the anode. The electrolyte is kept extremely thin to allow for the subsequent interpenetration into the structure by the cathode material and is anticipated to be extraordinarily insulating and pin-hole free. The strict demands on the electrolyte form the basis for additional intellectual property protection.
Energy Density
Power Density
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